Sequential Birch Reduction—Allylation and Cope Rearrangement of o-Anisic Acid Derivatives.
نویسندگان
چکیده
منابع مشابه
Sequential Birch Reduction-Allylation and Cope Rearrangement of O-Anisic Acid Derivatives
A new method for the construction of quaternary centers on cycloalkane rings is reported. The Cope rearrangement of 4methyl-2-allyl-2-(N-pyrrolidinyl)-carboxamide-3-cyclohexenone yields 4-methyl-4allyl-2-(N-pyrrolidinyl)-carboxamide-2-cyclohexenone in high yield. The rearrangement substrates are easily generated from Birch reduction-allylation of o-anisic acid derivatives. © 2012 Elsevier Scien...
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ژورنال
عنوان ژورنال: ChemInform
سال: 2005
ISSN: 0931-7597,1522-2667
DOI: 10.1002/chin.200506090